• Rio de Janeiro Brasil
  • 14-18 Novembro 2022

CHEMICAL CHARACTERIZATION OF SACHA INCHI CULTIVATED IN TAMBO-CAUCA-COLOMBIA

Autores

Sarria-villa, R. (UNIVERSIDAD DEL CAUCA) ; Orozco, M. (UNIVERSIDAD NACIONAL ABIERTA Y A DISTANCIA) ; Gallo, J.A. (UNIVERSIDAD DEL CAUCA)

Resumo

Catio-215 and FR-16 varieties of sacha inchi from Tambo Cauca-Colombia were analyzed. Husk and seed samples were analyzed. Chemical analyzes carried out on the samples were: humidity, ashes, ethereal extract, protein, crude fiber, and non-nitrogenous extract (NNE). Results indicate a range of humidity of 10-14%; 2- 4%, 10-14%; 4-7%, ashes of 1-3%; 1-3%, 1-3%; 1-3%, ethereal extract between 0-2%; 21-25%, 0-2%; 10-12%, protein of 1-5%; 19-23%, 3-6%; 22-26%, crude fiber of 38- 42%; 1-5%, 32-36%; 2-6%, non-nitrogenous extract 38-42%; 42-46%, 44-48%; 52.56% to husk and seed of catio-215 and FR-16 varieties respectively. The results indicate an interest in the production and extraction of vegetable oil.

Palavras chaves

Sacha inchi; Proximal analysis; Vegetable oil

Introdução

Sacha inchi (Plukenetia Volubilis), is a wild oil-bearing plant, whose seeds (lenticular in appearance, laterally compressed, and brown with irregular darker spots) have a high protein value and a high content of polyunsaturated fatty acids compared to all oilseeds used in the world (Gómez, 2005). The Sacha inchi seed is the part with the highest value because derivatives are obtained in sectors such as food since oil is obtained by pressing; pharmaceuticals, for the manufacture of sacha inchi capsules, and in cosmetics, in the manufacture of anti-wrinkle cream (Sathe et al., 2002; IAP, 2009). The analysis of the chemical composition of the by-products gives indications that they are potential nutritional sources, for which, as an alternative, their use as fertilizer, and food supplements for animal or human food consumption has been studied (Sathe et al., 2002). According to the United Nations report in 2021, “Its cultivation in the Colombian countryside is relatively new. In June 2021, the government agency ProColombia reported “The Sacha inchi is cultivated by more than 1,100 farmers located in 22 departments of Colombian territory, among which are: Caquetá, Córdoba, Arauca, Antioquia, the Coffee Region, Huila, and Tolima. The growth of the Sacha inchi industry in the Cauca department and its potential use as a substitute for illicit crops would generate economic development in the region, either with the transformation of the raw material into oil, food supplements, and/or cosmetics. These processes are supported and/or accompanied by the academy which provides technical knowledge that can provide better conditions for the production of plants, the classification of the varieties obtained, the chemical composition of each of the products, and quality analysis of the products obtained.

Material e métodos

Methodology Sacha inchi seeds of the cross varieties (catio-215 and FR-16) underwent a proximal analysis, which consisted of the determination of moisture, ashes, ether extract, fiber, and crude protein. The analysis was performed in triplicate (Benítez et al., 2015). Samples Given the granular consistency of the sacha inchi seed, the sample was chosen using the quartering method (3 repetitions) for each of the parts (husk, and seed). With the samples already separated, the conditioning was carried out, which consisted of crushing and subsequent screening (1mm) of the sample to homogenize it for subsequent analysis. Reagents Hydrochloric Acid 37% pure pharma grade PanReac, Sulfuric Acid 96% for analysis, ISO PanReac, Sodium hydroxide anhydrous pellets for analysis carlo erba, Boric Acid for analysis PanReac, Kjeldhal Catalyst with Selenium powder Chemí, Mixed Indicator 5 Tashiro Chemí, Ethanol absolute for analysis, ACS ISO.

Resultado e discussão

Sacha inchi is an oily plant, from which its star-shaped fruit is taken and the seeds are extracted, these are of commercial interest because they have a content of unsaturated fatty acids suitable for human consumption, and this has led to the wide development and expectation of the crop in the Cauca department. Samples of seeds and husk of the catio-215 and FR-16 varieties were analyzed, which allowed the respective comparisons to be made. In Colombia, sacha inchi (Plukenetia volubilis) has a wide potential for agro- industrial development; However, some varieties such as Catio-215 and FR-16 cultivated in the department of Cauca, in the municipalities of Tambo and Timbio, the real value of the nut and its by-products for use in nutrition is not known. both animal and human. The objective of the study was to determine the nutritional composition of the seeds and the hull of two varieties grown in the department of Cauca, as well as to determine the content of acidity index, relative density, iodine index, peroxide index and saponification index of the sacha inchi oil Statistically significant differences (p > 0.05) were found for the nutritional components evaluated in seed and husk of both varieties of sacha inchi. The catio-215 seeds presented a higher percentage of protein and fat in relation to FR-16, 22.78% and 21.85% respectively, compared to 0.71% fat and 4.87% protein in the FR -16 variety (Table 1). On the contrary, the husk of the FR-16 variety is the fat that presents the highest percentage of and protein in relation to the catio-215 variety, which allows us to see a relationship between the analyzed materials, a higher percentage of fat and protein in the nut, lower percentage of both in the shell. Sacha inchi nut protein is a rich source of memories: lysine and tyrosine, lysine being an amino acid that acts as a precursor to carnitine, which is necessary for fat metabolism and energy production. The sacha inchi protein of both species has the potential to be used in human nutrition due to its high nutritional value, the presence of antinutrients must be verified. Table 1. Chemical analysis of catio-215 and FR-16 sacha inchi varieties Figure 1. Sacha inchi seed (FR-16) from Tambo-Cauca-Colombia. Table 2 shows the acid number of this oil is 1.63 mg KOH/g. According to (FAO/WHO, 2015) it should not be greater than 4 mgNaOH/g for cold-pressed vegetable oils, this is due to the fact that it does not present refining, values very similar to those of olive oil, which according to (Paucar-Menacho et al, 2015) has a value of 1.14 mgNaOH/g. The density of 0.92 shows that this oil is light due to the amount of unsaturated fatty acids present (Gutiérrez et al., 2011). The iodine index relates the degree of saturation, a result of 10.09 compared to 56.15 for olive oil, this could be due to inadequate storage of the oil once it was extracted by pressing. Table 2. Physicochemical characteristics of Sasha inchi oil

Figure 1. Sacha inchi seed (FR-16) from Tambo-Cauca-Colombia.



Table 1. Chemical analysis of catio-215 and FR-16 sacha inchi varietie



Conclusões

The fruit of the sacha inchi presents high amounts of polyunsaturated fatty acids, however, the percentage differs according to the variety and the factors that can affect the development of the crop, there is a great difference between catio-215 and FR-16 varieties. It is observed how characteristics such as humidity or the percentage of ash are key to the quality and quantity of polyunsaturated fatty acids that it can provide, remembering that this is the greatest interest of the commercial plant, and that according to its quality it can not only be used in the food industry but also in cosmetics and pharmaceuticals.

Agradecimentos

The authors thank to groups GIQA, QPN, VRI-Unicauca, Proy ID 5491 (conv. interacción social), Department of Chemistry-Unicauca (501100005682) for their collaboration in the development of this research. Cooperativa Sacha Tambo.

Referências

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Reportaje escrito por Lucía Benavente para Noticias ONU https://news.un.org/es/story/2021/10/1498782

https://procolombia.co/noticias/el-aceite-colombiano-de-sacha-inchi-pisa-fuerte-en-el-mercado-internacional

Patrocinador Ouro

Conselho Federal de Química
ACS

Patrocinador Prata

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Patrocinador Bronze

LF Editorial
Elsevier
Royal Society of Chemistry
Elite Rio de Janeiro

Apoio

Federación Latinoamericana de Asociaciones Químicas Conselho Regional de Química 3ª Região (RJ) Instituto Federal Rio de Janeiro Colégio Pedro II Sociedade Brasileira de Química Olimpíada Nacional de Ciências Olimpíada Brasileira de Química Rio Convention & Visitors Bureau